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Praseodymium (Pr) - Chemical properties, Health and Environmental effects
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Chemical properties of praseodymium
- Health effects of praseodymium -
Environmental effects of
praseodymium
Atomic number
59
Atomic mass
140.91 g.mol -1
Electronegativity according to Pauling
1.1
Density
6.8 g.cm-3 at 20°C
Melting point
931 °C
Boiling point
3512 °C
Vanderwaals radius
unknown
Ionic radius
0.101 nm (+3)
Isotopes
5
Electronic shell
[ Xe ] 4f3 6s2
Energy of first ionisation
522 kJ.mol -1
Energy of second ionisation
1016 kJ.mol -1
Energy of third ionisation
2082.4 kJ.mol -1
Energy of fourth ionisation
3752 kJ.mol -1
Energy of fifth ionisation
5534 kJ.mol -1
Standard Potential
- 2.47 V
Discovered by
von Welsbach in 1885
Praseodymium
Praseodymium is a soft malleable, silvery-yellow metal. It is a member of the
lanthanide group of the periodic table of elements. It reacts slowly with
oxygen: when exposed to air it forms a green oxide that does not protect it from
further oxidation. It is more resistant to corrosion in air the other rare
metals, but it still needs to be stored under oil or coated with plastic. It
reacts rapidly with water.
Applications
A major use of the metal is in a pyrophoric alloy used in cigarettes lighter
flints. Praseodymium compounds have different uses: the oxide is used in carbon
electrodes for arc lighting, and it is know for its ability to give glass a nice
yellow colour. This glass filters out the infrared radiation, so it is used in
the goggles which protect the eyes of welders. The salts are used to colour
enamel and glass. Praseodymium can be used as alloying agent with magnesium to
create high strenght metals that are used in aircraft engines.
Praseodymium is one of the rare chemicals, that can be found in houses in equipment such as colour televisions, fluorescent lamps, energy-saving lamps and glasses. All
rare chemicals have comparable properties. The use of praseodymium is
still growing, due to the fact that it is suited to produce catalysers and to
polish glass.
Praseodymium in the environment
Praseodymium is one of the more abundant of rare-earth elements. It is four
time more abundant than tin. Praseodymium is usually
found only in two different kinds of ores.
The major commercial ores in which praseodymium is found are monazite and
bastnasite. The main mining areas are China, USA, Brazil, India, Sri Lanka and
Australia. Reserves of praseodymium are estimated to be around 2 million tonnes.
World production of praseodymium is about 2500 tonnes per year.
Health effects of praseodymium
Like all rare metals praseodymium is of low to moderate
toxicity. Soluble praseodymium salts are mildly toxic by ingestion, but
insoluble salts are non toxic. They are skin and eye irritants.Praseodymium is mostly dangerous in the working environment, due to the fact that damps and gasses can be inhaled with air. This can cause lung embolisms, especially during long-term exposure. Praseodymium can be a threat to the liver when it accumulates in the human body.
Environmental effects of praseodymium
Praseodymium is dumped in the environment in many different places, mainly by petrol-producing industries. It can also enter the environment when household equipment is thrown away. Praseodymium will gradually accumulate in soils and water soils and this will eventually lead to increasing concentrations in humans, animals and soil particles.
With water animals praseodymium causes damage to cell membranes, which has several negative influences on reproduction and on the functions of the nervous system.
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